Chem 高手請答~~

2007-04-28 7:56 am
1. Write a balanced redox equation for the following reaction by oxidation number method.

1. reaction between acidified potassium dichromate solution and sodium sulphite solution

有個step 我唔明 balance the change in oxidation number
Cr2O7 2- (aq) + 3SO3 2- ------> 2Cr 3+ + 3SO4 2-

呢個step 我唔多明白~ 應該係 Cr2O7 2- 同2Cr 3+ x2

點解Cr2O7 2- and 2Cr 3+ 唔需 x2??

3SO3 2- and 3SO4 2- 就有x左3?


請寫成個steps and explain 丫~ plz!!!

請詳細一點,,和簡單一點 呢課我係岩岩新教~ thz~
更新1:

不是用half equation 是用 oxidation number method.~~

回答 (2)

2007-04-28 8:53 am
✔ 最佳答案
要明白點解要 x3

首先.你要明白dichromate(Cr2O7 2-)變Cr3+既half-equation.

即係甘: Cr2O7 2- + 14H+ + 6e- --> 2Cr3+ + 7H2O

1.) dichromate ion 變左 Cr3+ 之後會出 7H2O既reason係dichromate本身contains oxygen.
為左要令o個7個oxygen走.要加返7個H2O.
2.) 左邊有14H+係要balance返右邊H2O既Hydrogen. d H+既來源係 acidified potassium dichromate 入面acid contains既 H+.
3.) 而6粒electron(6e-)係due to個change of oxidation number.
Cr既oxidation number由 +6變 +3.中間既change 係3.
本來係要加3粒electron去balance 個charges既.
but because個product有2個Cr3+.so要將本來3粒既electron x2 變做6粒

remember that 呢個係reduction (Oxidizing agent)!!!!!!!

之後.就到sulphite (SO3 2-)既half-equation

即係甘: SO3 2- + H2O --> SO4 2- + 2H+ + 2e-

加H2O同H+既原理同dichromate ion一樣.
不過今次係1個H2O.因為只需1個oxygen就balance個equation.
electron都係照數oxidation number.今次相差2.所以加2粒

remember that 呢個係oxidation (Reducing agent)!!!!!!!
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至於最後.當然要將2條equation combine.
但係你會見到2邊electron既數目吾同.
甘樣既話redox reaction係冇可能發生的.
因為大家放既electron同收既electron有差距.
所以我地要將第2條equation x3.
等到兩條equation刀有6粒electron,
甘樣兩條equation就可以有redox reaction了.

Cr2O7 2- + 3SO3 2- + 14H+ + 3H2O ------> 2Cr 3+ + 3SO4 2- + 7H2O + 6H+


我都係岩岩教redox架咋.我只係中四學生.
教得吾好吾好見怪.吾明再ask la

2007-04-29 17:46:47 補充:
你要知SO3 2-點解係條equation度x3.首先1定要明half-equation ga.你要知道1個SO3 2-變1個SO4 2-會放2粒e-.但係Cr2O7 2-變2Cr 3 就要吸6粒e-.甘樣咪要3個SO3 2-先可以放6粒e-俾Cr2O7 2-變2Cr 3 lor.that's why 要x3.
參考: 自己
2007-04-28 8:47 am
寫half equation

8e- + Cr2O7 2- + 14H+ -> 2Cr3+ 7H2O
SO3 2- +H2O -> SO4 2- +2H+ 2e -

上面x1 + 下面x4

Cr2O7 2- + 6H+ 4SO3 2- -> 2Cr3+ + 3H2O+ 4SO4 2-

半夜答好似望你上面寫野就覺得自己錯... 淆底了-.-..
參考: 腦塞車諗到的答案...


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