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when we breathe in (inspiration), the diaphragm muscle contracts and become flattened, the external intercostal muscles also contract to move the rib cage upwards and outwards. both will cause an increase in thoracic volume. the pressure in thoracic cavity decrease and become lower than atmospheric pressure. Thus air from atmosphere rush into the lungs and the lung is inflated.
when we breath out (expiration), the diaphragm muscle relax and cause it become dome-shaped. the external interconstal muscle also relax and cause the rib cage move inwards and downwards. both cause a decrease in thoracic volume. the pressure in thoracic cavity increase and become higher than the atmospheric pressure. thus air is forced out from the lungs and the lung become deflated.
athletes' lungs aren't bigger, but their tidal volume and vital capacity will be larger than us due to their training. so they can breathing volume will be greater to facilitate gaseous exchange (O2 and CO2) to support the energy need for and remove wastes from exercise.