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Scout was a term used in the military as the soilders who sent out to the front line to search for enemies. As the founder (Lord Baden-Powell) of the Scouting movement was a military man, he used the word to describe the trainings he provided to boys during peace time and hence Boy Scout.
The first chapter of his book "Scouting for Boys" published in 1908 has made this very clear:
"WHAT SCOUTS ARE"
I SUPPOSE EVERY Boy wants to help his country in some way or other. There is a way by which he can so do easily, and that is by becoming a Boy Scout.
A scout in the army, as you know, is generally a soldier who is chosen for his cleverness and pluck to go out in front to find out where the enemy is, and report to the commander all about him.
But, besides war scouts, there are also peace scouts-men who in peace time carry out work which requires the same kind of pluck and resourcefulness.
These are the frontiersmen of the world."......