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Cobalt is a hard, lustrous, silver-gray metal, a chemical element with symbol Co. It is found in various ores, and is used in the preparation of magnetic, wear-resistant, and high-strength alloys. Its compounds are used in the production of inks, paints, and varnishes.
27
iron ← cobalt → nickel
-
↑
Co
↓
Rh
圖片參考:
http://upload.wikimedia.org/wikipedia/commons/9/9e/Co-TableImage.png
Periodic Table - Extended Periodic Table
General
Name, Symbol, Number
cobalt, Co, 27
Chemical series
transition metals
Group, Period, Block
9, 4, d
Appearance
metallic with gray tinge
圖片參考:
http://upload.wikimedia.org/wikipedia/commons/thumb/5/51/Co%2C27.jpg/125px-Co%2C27.jpg
Atomic mass
58.933195(5) g·mol−1
Electron configuration
[Ar] 4s2 3d7
Electrons per shell
2, 8, 15, 2
Physical properties
Density (near r.t.)
8.90 g·cm−3
Liquid density at m.p.
7.75 g·cm−3
Melting point
1768 K
(1495 °C, 2723 °F)
Boiling point
3200 K
(2927 °C, 5301 °F)
Heat of fusion
16.06 kJ·mol−1
Heat of vaporization
377 kJ·mol−1
Heat capacity
(25 °C) 24.81 J·mol−1·K−1
Vapor pressure
P(Pa)
1
10
100
1 k
10 k
100 k
at T(K)
1790
1960
2165
2423
2755
3198
Atomic properties
Crystal structure
hexagonal
Oxidation states
2, 3
(amphoteric oxide)
Electronegativity
1.88 (Pauling scale)
Ionization energies
(more)
1st: 760.4 kJ·mol−1
2nd: 1648 kJ·mol−1
3rd: 3232 kJ·mol−1
Atomic radius
135 pm
Atomic radius (calc.)
152 pm
Covalent radius
126 pm
Miscellaneous–
Magnetic ordering
ferromagnetic
Electrical resistivity
(20 °C) 62.4 n Ω·m
Thermal conductivity
(300 K) 100 W·m−1·K−1
Thermal expansion
(25 °C) 13.0 µm·m−1·K−1
Speed of sound (thin rod)
(20 °C) 4720 m/s
Young's modulus
209 GPa
Shear modulus
75 GPa
Bulk modulus
180 GPa
Poisson ratio
0.31
Mohs hardness
5.0
Vickers hardness
1043 MPa
Brinell hardness
700 MPa
CAS registry number
7440-48-4
Selected isotopes
Main article: Isotopes of cobalt
iso
NA
half-life
DM
DE (MeV)
DP
56Co
syn
77.27 d
ε
4.566
56Fe
57Co
syn
271.79 d
ε
0.836
57Fe
58Co
syn
70.86 d
ε
2.307
58Fe
59Co
100%
Co is stable with 32 neutrons
60Co
syn
5.2714 years
β-
2.824
60Ni
References
Notable characteristics
Cobalt is ferromagnetic with atomic number 27. The Curie temperature is of 1388 K with 1.6~1.7 Bohr magnetons per atom. It is frequently associated with nickel, and both are characteristic ingredients of meteoric iron. Mammals require small amounts of cobalt salts. Cobalt-60, an artificially produced radioactive isotope of cobalt, is an important radioactive tracer and cancer-treatment agent. Cobalt has a relative permeability two thirds that of iron. Metallic cobalt commonly presents a mixture of two crystallographic structures hcp and fcc with a transition temperature hcp→fcc of 722 K.
Common oxidation states of cobalt include +2 and +3, though +1 is also seen.
[edit] Applications
Alloys, such as:
Superalloys, for parts in gas turbine aircraft engines.
Corrosion- and wear-resistant alloys.
High speed steels.
Cemented carbides (also called hard metals) and diamond tools.
Magnets and magnetic recording media.
Alnico magnets.
Catalysts for the petroleum and chemical industries.
Electroplating because of its appearance, hardness, and resistance to oxidation.
Drying agents for paints, varnishes, and inks.
Ground coats for porcelain enamels.
Pigments (cobalt blue and cobalt green).
圖片參考:
http://upload.wikimedia.org/wikipedia/commons/thumb/7/7a/Bristol.blue.glass.arp.750pix.jpg/145px-Bristol.blue.glass.arp.750pix.jpg
圖片參考:
http://en.wikipedia.org/skins-1.5/common/images/magnify-clip.png
Cobalt blue glass
http://en.wikipedia.org/wiki/Cobalt