By means of permutation:
For 52 cards, there are 52! possibilities of arrangement of the cards where ! means the factorial operation.
Now, let A be the card of ace of spades and then take a look at the diagram below:
圖片參考:
http://i117.photobucket.com/albums/o61/billy_hywung/Maths/Probphlmf.jpg
【此圖乃本人自製圖片,未經本人同意勿擅自連結或使用】
In fact, card A can be from position 1 to 39 for any favourable outcome (since at least 13 positiosn should be left at the end for those hearts), i.e. 1 ≦ r ≦ 39
Now, for each value of r, if we want a favourable outcome, the preceding r-1 positions before A must be filled by non-heart and for the remaining 52 - r position behind A, the arrangement can be random.
So the general expression of number of permutations for any 1 ≦ r ≦ 39 is:
圖片參考:
http://i117.photobucket.com/albums/o61/billy_hywung/Maths/Probphlmf2.jpg
And hence the final probability will be summing up all these values for 1 ≦ r ≦ 39 divided by the total number of possible permutations, i.e.
圖片參考:
http://i117.photobucket.com/albums/o61/billy_hywung/Maths/Probphlmf3.jpg
∴ The probability, if expressed in percentage, is about 7.14%.