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絕對有
Most substances have a pH value of 0-14, but not all. An example is acid mine runoff, with a molar concentration of 3981 M and a pH = -3.6.
For those substances which are extremely acid, we call it superacid (
http://en.wikipedia. org/wiki/Superacid ). For a substance which is extremely alkaline, we call it superbase (
http://en.wikipedia. org/wiki/Superbase ).
superacid such as HSO3F
10^6 - 10^10 more acidic than HNO3, H2SO4
non aqueous